Thermochemical conversion of biomass volatiles via chemical looping: Comparison of ilmenite and steel converter waste materials as oxygen carriers

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چکیده

Two oxygen carriers were tested with respect to chemical looping combustion (CLC) and gasification (CLG). Ilmenite, a natural ore composed mainly of iron–titanium oxide, LD Slag, an iron-based industrial waste, investigated at 850 900 °C in continuous operation 0.3 kW chemical-looping reactor system using synthetic biomass volatiles as fuel. CLC CLG conditions simulated the fuel by changing flow rates. In case ilmenite syngas yield methane conversion increased rate. Consequently, hydrocarbon ratio was higher for ilmenite. Methane improved both increasing operating temperature. Oxygen release observed Slag. The H2/CO between 0.7 0.8 flows. With CLC, showed gas than slag. Analysis particles revealed that possessed better mechanical properties formed less dust compared Slag during

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ژورنال

عنوان ژورنال: Fuel

سال: 2022

ISSN: ['0016-2361', '1873-7153']

DOI: https://doi.org/10.1016/j.fuel.2021.122638